In the Tuesday evening matches involving English sides, Jose Mourinho takes charge of his first Champions League game as Tottenham boss with the visit of Olympiakos while Manchester City host Shakhtar Donetsk.

Elsewhere, Real Madrid and PSG meet in a titanic clash at the Bernabeu and Juventus play Atletico Madrid.

On Wednesday, Klopp's mob play Napoli at Anfield and Chelsea are in Valencia while Barcelona and Borussia Dortmund clash at the Nou Camp.